melamine trisulfonic acid catalyzed regioselective nitration of aromatic compounds under solvent-free conditions

نویسندگان

jalal albadi

young research club, gachsaran branch, islamic azad university, gachsaran, iran farhad shirinib

department of chemistry, college of science, university of guilan, rasht, iran masoumeh abedini

department of chemistry, college of science, university of guilan, rasht, iran tayebeh seiadatnasab

department of chemistry, gachsaran branch, islamic azad university, gachsaran, iran

چکیده

a simple, mild and efficient method for the regioselective nitration of various aromatic compounds usingpoly(4-vinylpyridinium nitrate) (p4vpyn) in the presence of melamine trisulfonic acid (mtsa), is reported.this method provides several advantages such as good selectiveity between ortho and para positions ofaromatic compounds, clean procedure, simple work-up, short reaction times, solvent-free conditions andhigh yields of products. this methodology is useful for nitration of activated and deactivated aromatic rings.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Melamine trisulfonic acid catalyzed regioselective nitration of aromatic compounds under solvent-free conditions

A simple, mild and efficient method for the regioselective nitration of various aromatic compounds usingpoly(4-vinylpyridinium nitrate) (P4VPyN) in the presence of melamine trisulfonic acid (MTSA), is reported.This method provides several advantages such as good selectiveity between ortho and para positions ofaromatic compounds, clean procedure, simple work-up, short reaction times, solvent-fre...

متن کامل

Melamine trisulfonic acid as a highly efficient catalyst for the synthesis of polyhydroquinolines under solvent-free conditions

A highly efficient, simple and clean solvent-free protocol for the synthesis of polyhydroquinolines is described. The one-pot multi-component condensation reaction between arylaldehydes, dimedone (5,5-dimethylcyclohexane-1,3-dione), β-ketoesters and ammonium acetate in the presence of catalytic amount of (2.5 mol%) melamine trisulfonic acid (MTSA) as a recyclable, green and attractive sulfonic ...

متن کامل

Reusable Silica supported Perchloric acid and potassium bisulphate as green catalysts for thiocyanation of aromatic compounds under solvent free conditions

Reusable silica supported perchloric acid and potassium bisulphate have been prepared and explored as green catalysts for thiocyanation of aromatic compounds under conventional and solvent free microwave assisted conditions. The microwave assisted protocol exhibited remarkable rate accelerations and offered selective thiocyanation of aromatic and hetero aromatic compounds in good yields. Reacti...

متن کامل

TiO2 nanoparticles/melamine Tri sulfonic acid for biginelli syntheis under solvent-free conditions

TiO2 nanoparticles/melamine Tri sulfonic acid (MTSA) supported on silica gel as an efficient catalytic system for simple, one pot, solvent-free and environmentally benign process for synthesis of dihydropyrimidines via Biginelli reaction at 110 °C is described. It was found that the catalyst is reusable and exhibited remarkable activity. The catalyst can be easily separated and reused several t...

متن کامل

TiO2 nanoparticles/melamine Tri sulfonic acid for biginelli syntheis under solvent-free conditions

TiO2 nanoparticles/melamine Tri sulfonic acid (MTSA) supported on silica gel as an efficient catalytic system for simple, one pot, solvent-free and environmentally benign process for synthesis of dihydropyrimidines via Biginelli reaction at 110 °C is described. It was found that the catalyst is reusable and exhibited remarkable activity. The catalyst can be easily separated and reuse...

متن کامل

TiO2 nanoparticles/melamine Tri sulfonic acid for biginelli syntheis under solvent-free conditions

TiO2 nanoparticles/melamine Tri sulfonic acid (MTSA) supported on silica gel as an efficient catalytic system for simple, one pot, solvent-free and environmentally benign process for synthesis of dihydropyrimidines via Biginelli reaction at 110 °C is described. It was found that the catalyst is reusable and exhibited remarkable activity. The catalyst can be easily separated and reused several t...

متن کامل

منابع من

با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید


عنوان ژورنال:
journal of the iranian chemical research

جلد ۵، شماره ۳، صفحات ۱۵۵-۱۵۹

میزبانی شده توسط پلتفرم ابری doprax.com

copyright © 2015-2023